Here is a list of methods that can be used to identify mercury in different samples.
Natural waters
Chromatographic methods:
1. Gas chromatography Volatile Hg species are stripped from the sample solution and pre-concentrated, prior to separation. The trapped mercury derivatives are then released thermally and transferred quantitatively to the GC for separation.
2. High performance liquid chromatographic (HPLC) separation
A reversed phase column based on alkyl-silica and a mobile phase containing an organic modifier, together with a chelating or ion pair reagent (and in some cases a pH buffer) are usually used.
3. Capillary electrophoresis
Uses charge and frictional forces for the separation of Hg species.
Air
1. Selective adsorption methods
2. Chromatographic methods
Biological samples
1. Gas chromatography
2. HPLC
In the 1950s, in Minamata, Japan, bizarre behaviour of humans and even cats, (such as shouting uncontrollably, slurred speech) led to the investigation of what had caused this huge epidemic. Researchers identified the disease as heavy-metal poisoning caused by eating the fish and shellfish of Minamata Bay. Further investigations carried out suggested that mercury from the production process of acetaldehyde had spilled into the bay and entered the marine food chain.
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